全文获取类型
收费全文 | 66148篇 |
免费 | 7260篇 |
国内免费 | 5820篇 |
专业分类
化学 | 24671篇 |
晶体学 | 302篇 |
力学 | 4584篇 |
综合类 | 1407篇 |
数学 | 26241篇 |
物理学 | 22023篇 |
出版年
2023年 | 545篇 |
2022年 | 890篇 |
2021年 | 1910篇 |
2020年 | 1590篇 |
2019年 | 1624篇 |
2018年 | 1398篇 |
2017年 | 1627篇 |
2016年 | 2006篇 |
2015年 | 1861篇 |
2014年 | 2899篇 |
2013年 | 4570篇 |
2012年 | 3194篇 |
2011年 | 3748篇 |
2010年 | 3428篇 |
2009年 | 4220篇 |
2008年 | 4340篇 |
2007年 | 4627篇 |
2006年 | 3876篇 |
2005年 | 3211篇 |
2004年 | 2686篇 |
2003年 | 2679篇 |
2002年 | 2406篇 |
2001年 | 2178篇 |
2000年 | 1784篇 |
1999年 | 1532篇 |
1998年 | 1402篇 |
1997年 | 1195篇 |
1996年 | 1136篇 |
1995年 | 991篇 |
1994年 | 927篇 |
1993年 | 833篇 |
1992年 | 768篇 |
1991年 | 565篇 |
1990年 | 482篇 |
1989年 | 411篇 |
1988年 | 389篇 |
1987年 | 329篇 |
1986年 | 311篇 |
1985年 | 478篇 |
1984年 | 358篇 |
1983年 | 218篇 |
1982年 | 411篇 |
1981年 | 552篇 |
1980年 | 482篇 |
1979年 | 540篇 |
1978年 | 417篇 |
1977年 | 329篇 |
1976年 | 292篇 |
1974年 | 94篇 |
1973年 | 187篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
22.
Chinese Annals of Mathematics, Series B - In the present article, the authors find and establish stability of multiplier ideal sheaves, which is more general than strong openness. 相似文献
23.
近年来,设计和合成高性能非富勒烯受体(NFAs)材料已经成为太阳能电池研究领域的前沿课题。基于DA'D型稠环结构的NFAs由于具有吸光系数高、能级和带隙可调、结构易于修饰、分子可高效合成、光电学性能优异等优点而受到了越来越广泛的关注。在短短7年的时间里,能量转换效率(PCE)从3%~4%提高到18%。2019年初邹应萍等报道了一个优秀的受体分子Y6,与PM6共混制备单结电池,获得了15.7%的能量转换效率。Y6类受体材料的中心给电子单元为DA'D型稠环结构,缺电子单元(A')通过氮原子与两个给电子单元(D)并联形成稠环结构,这有助于降低前线分子轨道能级并增强吸收,同时与氮相连的两个烷基链和位于噻吩并噻吩β位的两个侧链则有助于提高溶解度及调节结晶性。自Y6问世以来,人们对分子的结构剪裁进行了深入的研究,并报道了数十种新的结构。在这些新的受体中,DA'D部分的结构裁剪对提高器件效率和太阳能电池的性能起着至关重要的作用。本文对A'、D单元和侧链结构修饰的研究进展进行了综述。通过选择几组受体,对最近报道的分子进行分类,并将它们的光学、电化学、电学和光电性质与精确的结构修饰相关联,从而对结构-性能关系进行全面概述。 相似文献
24.
SongIl Ri 《Indagationes Mathematicae》2018,29(3):962-971
The aim of this paper is to present a new idea to construct the nonlinear fractal interpolation function, in which we exploit the Matkowski and the Rakotch fixed point theorems. Our technique is different from the methods presented in the previous literatures. 相似文献
25.
Umie F.M. Haziz Rosenani A. Haque Shun-Ze Zhan Hassan H. Abdallah Mohd R. Razali 《应用有机金属化学》2020,34(10):e5818
The synthesis and characterizations for a series of dinuclear gold (I)-di-NHC complexes, 1–8 through the trans-metalation method of their respective silver (I)-di-NHC complexes, i–viii are reported (where NHC = N-heterocyclic carbene). The successful complexation of a series of unusual non-symmetrical and symmetrical di-NHC ligands, 3,3'-(ethane-1,2-diyl)-1-alkylbenzimidazolium-1'-butylbenzimidazolium (with alkyl = methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, benzyl) with the gold (I) ions are suggested by elemental analysis, Fourier transform-infrared, 1H- and 13C-NMR data. The 13C-NMR spectra of 1–8 show a singlet sharp peak in the range of 190.00–192.00 ppm, indicating the presence of a carbene carbon that bonded to the gold (I) ion. From single crystal X-ray diffraction data, the structure of complex 6 with the formula of [di-NHC-Au (I)]2·2PF6 is obtained [where NHC = 3,3'-(ethane-1,2-diyl)-1-hexylbenzimidazolium-1'-butylbenzimidazolium]. The photophysical study in solid state of 6 displays an intense photoluminescence with a strong emission maxima, λem = 480 nm, upon excitation at 340 nm at room temperature. Interestingly, the emission maximum at 77 K shows a structural character with a strong peak at 410 nm, a medium at 433 nm and a weak at 387 nm, accompanied by a tail band to about 500 nm. 相似文献
26.
Johannes C. B. Dietschreit Annika Wagner T. Anh Le Philipp Klein Prof. Dr. Hermann Schindelin Prof. Dr. Till Opatz Prof. Dr. Bernd Engels Prof. Dr. Ute A. Hellmich Prof. Dr. Christian Ochsenfeld 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(31):12769-12773
The absence of fluorine from most biomolecules renders it an excellent probe for NMR spectroscopy to monitor inhibitor–protein interactions. However, predicting the binding mode of a fluorinated ligand from a chemical shift (or vice versa) has been challenging due to the high electron density of the fluorine atom. Nonetheless, reliable 19F chemical-shift predictions to deduce ligand-binding modes hold great potential for in silico drug design. Herein, we present a systematic QM/MM study to predict the 19F NMR chemical shifts of a covalently bound fluorinated inhibitor to the essential oxidoreductase tryparedoxin (Tpx) from African trypanosomes, the causative agent of African sleeping sickness. We include many protein–inhibitor conformations as well as monomeric and dimeric inhibitor–protein complexes, thus rendering it the largest computational study on chemical shifts of 19F nuclei in a biological context to date. Our predicted shifts agree well with those obtained experimentally and pave the way for future work in this area. 相似文献
27.
《Mathematische Nachrichten》2018,291(8-9):1177-1190
We introduce homogeneous Besov and Triebel–Lizorkin spaces with variable indexes. We show that their study reduces to the study of inhomogeneous variable exponent spaces and homogeneous constant exponent spaces. Corollaries include trace space characterizations and Sobolev embeddings. 相似文献
28.
《Mathematical Methods in the Applied Sciences》2018,41(14):5691-5710
We consider a 2 time scale nonlinear system of ordinary differential equations. The small parameter of the system is the ratio ϵ of the time scales. We search for an approximation involving only the slow time unknowns and valid uniformly for all times at order O(ϵ2). A classical approach to study these problems is Tikhonov's singular perturbation theorem. We develop an approach leading to a higher order approximation using the renormalization group (RG) method. We apply it in 2 steps. In the first step, we show that the RG method allows for approximation of the fast time variables by their RG expansion taken at the slow time unknowns. Next, we study the slow time equations, where the fast time unknowns are replaced by their RG expansion. This allows to rigorously show the second order uniform error estimate. Our result is a higher order extension of Hoppensteadt's work on the Tikhonov singular perturbation theorem for infinite times. The proposed procedure is suitable for problems from applications, and it is computationally less demanding than the classical Vasil'eva‐O'Malley expansion. We apply the developed method to a mathematical model of stem cell dynamics. 相似文献
29.
《Wave Motion》2018
Large cable net structures have been widely applied in aerospace engineering due to the feature of light-weight, high packaging efficiency, and high thermal stability. Structural vibrations induced by a variety of disturbances are inevitable in the space environment, resulting in the requirement of effective vibration control strategies for large cable net structures. Since the large cable net structures have many closely spaced vibrational modes in the range of low frequencies, traditional modal based control may cause modal truncation and spillover problems. In this paper, a wave-based boundary control strategy is adopted and its effectiveness to control the vibration of cable net structures is investigated, by transfer function analysis and numerical methods. It is found that the structural vibration can be absolutely resisted by applying the wave-based boundary controllers onto all the exterior nodes, when disturbances come from the external boundaries of the cable net. Our results in this paper can provide a theoretical basis for the vibration control of large cable net structures. 相似文献
30.
We prove a sharp estimate for the k-modulus of smoothness, modelled upon a -Lebesgue space, of a function f in , where Ω is a domain with minimally smooth boundary and finite Lebesgue measure, , and . This sharp estimate is used to establish necessary and sufficient conditions for continuous embeddings of Sobolev-type spaces into generalized Hölder spaces defined by means of the k-modulus of smoothness. General results are illustrated with examples. In particular, we obtain a generalization of the classical Jawerth embeddings. 相似文献